Here's my justification for setting the nodal values to $g(\mathbf{x})$. There might be some details missing because this is an online answer and not a math paper.
Let's start with the homogeneous variational problem of finding $u \in V$ such that
$$ a(u,v) = \mathcal{B}(v) \quad \forall \quad v \in V $$ where $V$ is the space of $L_2$ functions that vanish at $\Gamma_D$. Let's assume for simplicity the problem is 2D:
Then the Galerkin approximation involves writing both $u$ and $v$ as linear combinations of 32 shape functions $h_j(\mathbf{x})$ times the nodal values
$u_j$ and $v_j$ $$ u(\mathbf{x}) = \sum_{j=1}^{32} h_j(\mathbf{x}) \cdot u_j = H \cdot \mathbf{u} $$
$$ v(\mathbf{x}) = \sum_{j=1}^{32} h_j(\mathbf{x}) \cdot v_j = H \cdot \mathbf{v} $$
for a matrix $H \in \mathbb{R}^{1 \times 32}$ such that the problem can be cast in matrix form as
$$ A \cdot \mathbf{u} = \mathbf{b} $$ where the elements of the matrix $A$ are
$$ a_{i,j} = a(h_i,h_j) $$ and the elements of vector $\mathbf{b}$ are
$$ b_i = \mathcal{B}(h_i) $$
Note that since the $h_j(\mathbf{x})$ form a basis of $V$ they all vanish on $\Gamma_D$ so the solution $u(\mathbf{x})$ also vanishes on $\Gamma_D$. This procedure is right but it is inconvenient because it is not easy to find the right shape functions that vanish on $\Gamma_D$. We can simplify it by allowing nodes to exist on $\Gamma_D$
and "extending" the expansion of $u$ and $v$ with zeros for $j=33,34,35$:
$$ u_h(\mathbf{x}) = \sum_{j=1}^{32} h_j(\mathbf{x}) \cdot u_j + \sum_{j=33}^{35} h_j(\mathbf{x}) \cdot 0 = \tilde{H} \cdot \begin{bmatrix}\mathbf{u} \\ \mathbf{0}\end{bmatrix} $$
$$ v(\mathbf{x}) = \sum_{j=1}^{32} h_j(\mathbf{x}) \cdot v_j + \sum_{j=33}^{35} h_j(\mathbf{x}) \cdot 0 = \tilde{H} \cdot \begin{bmatrix}\mathbf{v} \\ \mathbf{0}\end{bmatrix} $$ for an extended matrix $\tilde{H} \in \mathbb{R}^{1 \times 35}$.
First, we note that these "extended" objects
$$ \tilde{\mathbf{v}} = \begin{bmatrix} \mathbf{v} \\ \mathbf{0} \end{bmatrix} \quad \tilde{{A}} = \begin{bmatrix} {A} & {C} \\ {D} & {E} \\ \end{bmatrix} \quad \tilde{\mathbf{u}} = \begin{bmatrix} \mathbf{u} \\ \mathbf{0} \end{bmatrix} \quad \tilde{\mathbf{b}} = \begin{bmatrix} \mathbf{b} \\ \mathbf{e} \end{bmatrix} $$ still represent the original Galerkin problem. In effect,
$$ \begin{aligned} \tilde{\mathbf{v}}^T \cdot \tilde{{A}} \cdot \tilde{\mathbf{u}} &= \tilde{\mathbf{v}}^T \cdot \tilde{\mathbf{b}} \\ \begin{bmatrix} \mathbf{v}^T & \mathbf{0}^T \end{bmatrix} \cdot \begin{bmatrix} {A} & {C} \\ {D} & {E} \\ \end{bmatrix} \cdot \begin{bmatrix} \mathbf{u} \\ \mathbf{0} \end{bmatrix} & = \begin{bmatrix} \mathbf{v}^T & \mathbf{0}^T \end{bmatrix} \begin{bmatrix} \mathbf{b} \\ \mathbf{e} \end{bmatrix} \\ \begin{bmatrix} \mathbf{v}^T & \mathbf{0}^T \end{bmatrix} \cdot \begin{bmatrix} {A} \cdot \mathbf{u} + {C} \cdot \mathbf{0} \\ {D} \cdot \mathbf{u} + {E} \cdot \mathbf{0} \\ \end{bmatrix} &= \begin{bmatrix} \mathbf{v}^T & \mathbf{0}^T \end{bmatrix} \begin{bmatrix} \mathbf{b} \\ \mathbf{e} \end{bmatrix} \\ \mathbf{v}^T \cdot {A} \cdot \mathbf{u} + \mathbf{0}^T \cdot {D} \cdot \mathbf{u} &= \mathbf{v}^T \cdot \mathbf{b} + \mathbf{0}^T \cdot \mathbf{e}\\ \mathbf{v}^T \cdot {A} \cdot \mathbf{u} &= \mathbf{v}^T \cdot \mathbf{b}\\ \end{aligned} $$
Since this identity must hold $\forall \mathbf{v}$, then ${A} \cdot \mathbf{u} - \mathbf{b} = 0$, which is the original homogeneous problem. We now need to prove that if we have
$$ {K} = \begin{bmatrix} {A} & {C} \\ {0} & {I} \\ \end{bmatrix} \quad \mathbf{f} = \begin{bmatrix} \mathbf{b} \\ \mathbf{0} \\ \end{bmatrix} $$ such that ${A} \cdot \mathbf{u} = \mathbf{b}$, where ${I}$ is the identity matrix of size $3 \times 3$, then the vector $\mathbf{\varphi}$ such that ${K} \cdot \mathbf{\varphi} = \mathbf{f}$ is equal to
$$ \mathbf{\varphi} = \begin{bmatrix} \mathbf{u} \\ \mathbf{0} \\ \end{bmatrix} $$
Indeed, let $\mathbf{\varphi} = \begin{bmatrix} \mathbf{\varphi}_1 & \mathbf{\varphi}_2 \end{bmatrix}^T$. Then ${K} \cdot \mathbf{\varphi}$ is
$$ \begin{bmatrix} {A} & {C} \\ {0} & {I} \end{bmatrix} \cdot \begin{bmatrix} \mathbf{\varphi}_1 \\ \mathbf{\varphi}_2 \end{bmatrix} = \begin{bmatrix} {A} \cdot \mathbf{\varphi}_1 + {C} \cdot \mathbf{\varphi}_2\\ {0} \cdot \mathbf{\varphi}_1 + {I} \cdot \mathbf{\varphi}_2 \end{bmatrix} = \begin{bmatrix} \mathbf{b}\\ \mathbf{0} \end{bmatrix} $$
From the second row, $\mathbf{\varphi}_2 = \mathbf{0}$. Replacing this result in the first row, ${A} \cdot \mathbf{\varphi}_1 = \mathbf{b}$. Therefore $\mathbf{\varphi}_1 = {A}^{-1} \cdot \mathbf{b} = \mathbf{u}$.
This part proves that putting a one in the diagonal of the stiffness matrix and a zero in the RHS vector in the rows corresponding to the nodes at $\Gamma_D$ is correct.
Now let's investigate non-homogeneous Dirichlet BCs. The "lifting" procedure from textbooks translates into finding $u_h \in V$ such that
$$ a(u_h,v) = \mathcal{B}(v) - a(u_g,v) \quad \forall \quad v \in V $$
where functions in $V$ vanish at $\Gamma_D$, and $u_g$ is a known function (i.e. a known lifting) that satisfies $u_g(\mathbf{x}) = g(\mathbf{x})$ for $\mathbf{x} \in \Gamma_D$. Note that the right-hand side of the formulation contains known functions only.
Now, let's take back the $u_g$ into the left-hand side (we have already assumed $a$ was bi-linear) then we have to solve
$$ a(u_h+u_g,v) = \mathcal{B}(v) $$
Let's first write the functions $u_h$ and $v$ over the whole set of nodes
$$ u_h(\mathbf{x}) = \sum_{j=1}^{32} h_j(\mathbf{x}) \cdot u_j + \sum_{j=33}^{35} h_j(\mathbf{x}) \cdot 0 = \tilde{H} \cdot \begin{bmatrix}\mathbf{u} \\ \mathbf{0}\end{bmatrix} $$
$$ v(\mathbf{x}) = \sum_{j=1}^{32} h_j(\mathbf{x}) \cdot v_j + \sum_{j=33}^{35} h_j(\mathbf{x}) \cdot 0 = \tilde{H} \cdot \begin{bmatrix}\mathbf{v} \\ \mathbf{0}\end{bmatrix} $$ for anotherthe "extended" matrix $\tilde{H}$ of size $1 \times 35$.
We then write the non-homogeneous part $u_g$ as
$$ u_h(\mathbf{x}) = \sum_{j=1}^{32} h_j(\mathbf{x}) \cdot 0 + \sum_{j=33}^{35} h_j(\mathbf{x}) \cdot g(\mathbf{x}_j) = \tilde{H} \cdot \begin{bmatrix}\mathbf{0} \\ \mathbf{g}\end{bmatrix} $$ so the sum $u_h + u_g$ is
$$ u_h(\mathbf{x}) + u_g(\mathbf{x}) = \tilde{H} \cdot \begin{bmatrix}\mathbf{u} \\ \mathbf{g}\end{bmatrix} $$
Now, the stiffness matrix of the first homogeneous problem was $A \in \mathbb{R}^{32 \times 32}$. We then extend it to a new matrix of size $35 \times 35$
$$ \begin{bmatrix} A & C \\ D & E \end{bmatrix} $$ such that the discretized problem is now
$$ \begin{aligned} \begin{bmatrix} \mathbf{v}^T & \mathbf{0}^T \end{bmatrix} \cdot \begin{bmatrix} A & C \\ D & E \end{bmatrix} \cdot \begin{bmatrix} \mathbf{u} \\ \mathbf{g} \end{bmatrix} &= \begin{bmatrix} \mathbf{v}^T & \mathbf{0}^T \end{bmatrix} \cdot \begin{bmatrix} \mathbf{b} \\ \mathbf{e} \end{bmatrix} \\ \begin{bmatrix} \mathbf{v}^T & \mathbf{0}^T \end{bmatrix} \cdot \begin{bmatrix} A \cdot \mathbf{u} + C \cdot \mathbf{g} \\ D \cdot \mathbf{u} + E \cdot \mathbf{g} \end{bmatrix} &= \begin{bmatrix} \mathbf{v}^T & \mathbf{0}^T \end{bmatrix} \cdot \begin{bmatrix} \mathbf{b} \\ \mathbf{e} \end{bmatrix} \\ \mathbf{v}^T \cdot A \cdot \mathbf{u} + \mathbf{v}^T \cdot C \cdot \mathbf{g} &= \mathbf{v}^T \cdot \mathbf{b} \end{aligned} $$ for all $\mathbf{u} \in \mathbb{R}^J$. That is to say,
$$ A \cdot \mathbf{u} + C \cdot \mathbf{g} = \mathbf{b} $$
Now you can prove as an exercise that if we have
$$ K = \begin{bmatrix} A & C \\ 0 & I \\ \end{bmatrix} \quad \mathbf{f} = \begin{bmatrix} \mathbf{b} \\ \mathbf{g} \\ \end{bmatrix} $$ such that $A \cdot \mathbf{u} + C \cdot \mathbf{g} = \mathbf{b}$, then the vector $\mathbf{\varphi}$ such that $K \cdot \mathbf{\varphi} = \mathbf{f}$ is equal to
$$ \mathbf{\varphi} = \begin{bmatrix} \mathbf{u} \\ \mathbf{g} \\ \end{bmatrix} $$