I use Bernstein polynomials in a collocation method to solve boundary value problems for ODEs and PDEs. They are quite interesting.
Convergence was exponential for some linear BVPs, but little slower compared to Chebyshev collocation, Legendre Galerkin, and Tau.
Here's the figure comparing convergence rates with some Chebyshev spectral methods. The example problem is linear BVP:
$ \frac{d^2u}{dx^2}-4\frac{du}{dx}+4u = e^x +C \;,\; x \in [-1,1]$
with homogenous Dirichlet BCs, and C is a constant $C=-4e/(1+e)^2$.
I also uploaded this figure to figshare.
If you want, you may check out the code I'm writing:
http://code.google.com/p/bernstein-poly/
And here's the arxiv paper I wrote about solving elliptic BVPs on a square using Bernstein polynomial collocation.
Last year they celebrated a centennial of Bernstein polynomials - one more interesting fact.